Here's some of my personal observations while caving...
Pips are the hardcore cavers. They go everywhere in a cave, except really, really deep. Once you get past a certain distance in a cave, the only bats you will see are pips. They're pretty obvious since they hang alone and are hard to disturb. They are also a very calm bat, and they are a weak flier that flitters up and down when they fly. If you're a half mile into a complex cave and see one bat hanging on the wall (which doesn't wake up as you pass by, eat lunch, change carbide, sing the Star Spangle Banner, etc.), that's an eastern pip.
My experience with the rest of the bats is that they stay closer to the entrance, but they they can still be 100s or 1000s of feet into the cave. I think a lot of depends on the cave passage.
Little Browns and Indianas hang in clusters. One of them hangs like shingles, and I think (but am not sure) it is the Little Browns. Big Browns also hang in clusters, but they're usually in smaller clusters. They're most obvious because of their size. There's not a lot of Big Browns around.
Big Browns are strong fliers. There about the size of a softball and will wake you up when they go by. Little Browns fly like they have a rocket up their ass. There is NOTHING weak about their flying and they can fly very straight. They'll actually have you trying to dig a hole in the floor of a crawlway to get away from them. We had to abort surveying a passage one time in Pendleton County because the Little Browns were buzzing us, and we were too busy trying to pull our heads back into our coveralls to do any surveying whatsoever.
Virginia big ears are just plain spastic. They roost in the biggest colonies, and they have a severe wiggle factor before they fly. Once they fly, they have to fly up and down, and up and down, and up and down the passage before they leave. They are a biggish bat and they flitter when they fly. Big ears are obvious because of their big ears, but not as obvious as you think, because they keep their ears curled up when they are roosting. Mostly they're obvious by their many large groups and their twitter factor. But the MOST obvious thing about a big-ear cave is that they are a guano bat. Guano is very slippery. Therefore, if you suddenly find yourself falling down, or waving one foot above your head while you slide out of control down a not-so-steep slope, you're probably in a big-ear cave. Big ears also like to roost in cracks in the cave roof, and that leaves an obvious red guano streak below the crack.
I think pips are my favorite bat. They go far into the cave, and they are so calm. And they'll roost in the most miserable crawlway you can find, and they're the ones that are usually covered with water drops. They're particularly nice to be with after you just spend ten minutes enduring a big-ear colony flying back and forth and back and forth before leaving the area.